Abstract
Abstract The influence of doping method on the electrical properties of polyacetylene are considered. Cis-polyacetylene was doped chemically and electrochemically with the (IrCl6)2-species. The conduction mechanism was found to be independent of doping method. Electrochemical doping, however, results in a more homogeneous distribution of dopant at the 15–200 angstrom level and a higher conducting material. Electrochemical doping also results in the incorporation of a non-hydrolyzed dopant species.
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