Abstract
A statistical analysis of molecular dipole moments within three space groups (P1, P1, and P21) was carried out. The magnitude of the molecular dipole moment does not vary significantly between centrosymmetric (P1) and noncentrosymmetric (P1 and P21) space groups and does not correlate with relative molecular orientations within the P21 space group. Thus, the high preference for organic molecules to crystallize in one of the centrosymmetric arrangements cannot be attributed to dipole-dipole interactions.
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