Abstract
The η 1-acetylide complexes (C 5H 5)ML 2(CCR) (M Fe, Ru; L PPh 3, L 2 Ph 2PCH 2CH 2PPh 2) are nucleophilic at the β-carbon and react with a variety of mild electrophiles to yield the corresponding disubstituted vinylidene complexes [(C 5H 5)ML 2 (CCR′) PF 6.
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