Abstract
The synthesis of zeolites from South African coal fly ash has been deemed a viable solution to the growing economical strain caused by the disposal of ash in the country. Two synthesis routes have been studied thus far namely the 2-step method and the fusion assisted process. Fly ash contains several elements originating from coal which is incorporated in the ash during combustion. It is vital to determine the final destination of these elements in order to unveil optimization opportunities for scale-up purposes. The aim of this study was to perform a material balance study on both synthesis routes to determine the distributional fate of these elements during the synthesis of zeolites. Zeolites were first synthesized by means of the two synthesis routes. The composition of all raw materials and products were determined after which an overall and elemental balance were performed. Results indicated that in the 2-step method almost all elements were concentrated in the solid zeolite product while during the fusion assisted route the elements mostly report to the solid waste. Toxic elements such as Pb, Hg, Al, As and Nb were found in both the supernatant waste and washing water resulting from each synthesis route. It has also been seen that large quantities of Si and Al are wasted in the supernatant waste. It is highly recommended that the opportunity to recycle this liquid waste be investigated for scale-up purposes. Results also indicate that efficiency whereby Si and Al are extracted from fused ash is exceptionally poor and should be optimized.
Highlights
The use of coal fired power stations dates back to the 1880s over 100 years ago [1]
Material balances were performed on two process routes whereby zeolites are synthesized from
The various elements originating from coal fly ash were tracked throughout the processes to determine their distributional fate
Summary
The use of coal fired power stations dates back to the 1880s over 100 years ago [1]. During the generation of electricity, the combustion of coal leads to the formation of incombustible solid residues.Of these residues, fly ash is the finest of the group of particulates and is produced on the largest scale [2].In a developing country such as South Africa, where coal supplies are abundant, the use of coal as source of energy forms a core part of economic growth. The use of coal fired power stations dates back to the 1880s over 100 years ago [1]. During the generation of electricity, the combustion of coal leads to the formation of incombustible solid residues. Of these residues, fly ash is the finest of the group of particulates and is produced on the largest scale [2]. In a developing country such as South Africa, where coal supplies are abundant, the use of coal as source of energy forms a core part of economic growth. In South Africa, a total of 36 Mt coal fly ash is produced annually from electricity generation alone [3]
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
