Distribution of Air pollutant Concentration and Ammonium conversion rate in Livestock Areas: Focusing on Boryeong

Abstract

Objectives:The association between the generation of fine particulate matter (PM2.5) and ammonia is well-established, highlighting the importance of managing ammonia as a primary means to reduce particulate matter. However, domestic research on ammonia emissions, particularly in livestock areas, which are major sources of ammonia, is insufficient. This study aims to contribute to pollutant management on a national scale by conducting air pollutant measurements and analyses in livestock areas. Methods:Real-time analysis and monitoring of air and weather conditions were carried out in Boryeong, Chungcheongnam-do, from 2021 to 2022. Statistical analysis was then employed to investigate the correlation between observed air pollutants (ammonia, nitrogen oxides, sulfur oxides, ozone and particle matters) and PM2.5. Results and Discussion:As a result of the analysis, the concentration of air pollutants in Boryeong showed a seasonal tendancy to decrease in summer and increase after that. Most substances such as NO2, SO2, and PM10 were observed within the standard values. In the case of ammonia, domestic air environment standards are not in place, but the annual average was found to be 61.5 ± 55.3 ppb, higher than in other research results. This discrepancy is attributed to the influence of nearby livestock houses. It was also observed that PM2.5 exceeded the annual standard value of 15 μg/m3 in spring (30.1 μg/m3), summer (18.3 μg/m3), autumn (25.3 μg/m3) and winter (31.7 μg/m3), respectively. During this period, ammonium (NH4+, 32.8%), nitrate (NO3-, 35.9%), and sulfate (SO42-, 19.7%) comprised the majority of particulate pollutants in PM2.5. The ammonia-ammonium conversion rate (NHR) was 0.08 annual average, and it was found that gas/ion phase changes were affected by seasonal weather conditions (temperature and relative humidity). As a result of analyzing the NHR according to the PM2.5 concentration, it was found that the higher the PM2.5 concentration, the higher the NHR. Furthermore, although the measurement area of this study exhibited high ammonia concentration, the NHR was low. This suggests that the contribution rate of ammonia to PM2.5 was relatively low compared to the other studies.Conclusion:As a result, there is a need for measures to reduce the high concentrations of ammonia in livestock areas. Simultaneously, considering the diverse mechanisms involved in particulate matter formation, it is suggested that management of pollutants such as nitrogen oxides, sulfur oxides including ammonia should be implemented.