Distinct scheelite REE geochemistry and 87Sr/86Sr isotopes in proximally- and distally-sourced metamorphogenic hydrothermal systems, Otago Schist, New Zealand

Abstract

The Otago Schist in New Zealand hosts orogenic tungsten (W) mineralization in two types. Proximally-sourced (“proximal”) mineralization in sub- to lower-greenschist facies Mesozoic metasedimentary rocks within the northern flank of the Otago Schist Belt comprise quartz-calcite veins with minor scheelite and few sulfides. Distally-sourced (“distal”) deposits are hosted in major crustal discontinuities within Mesozoic sub-greenschist to upper-greenschist facies metasedimentary rocks and are associated with abundant sulfides ± Au. In-situ trace element (particularly REE, Sr, Mo, Na, As) and in-situ 87Sr/86Sr compositions of scheelite show the scheelite occurring in these different mineralization types to be geochemically distinct. Proximal occurrences are characterised by scheelite with both heterogenous trace element and Sr isotope compositions displaying variations that can be linked to different veins, host rock types and scheelite generations. In contrast, scheelite within distal scheelite deposits tends to have fairly homogenous trace element and Sr isotopic ratios at the deposit to grain scale. The heterogenous compositions of proximal occurrences represent local derivation of diverse components from the sub-millimetre to meter scales and small extents of fluid flow, which resulted in a high sensitivity to sources and local rock compositions and thus limited large-scale equilibration of elemental and isotopic systematics within the scheelite they contain. The larger distal deposits formed by regional leaching by metamorphic fluids, probably at the greenschist-amphibolite facies boundary, followed by homogenisation as they ascended through the crust and leading to deposition of scheelite with rather uniform chemical characteristics. Our data re-enforce the model that tungsten mobility in the Otago Schist involved local-scale mobilisation of W in the shallow crust by breakdown of detrital rutile and scheelite at low metamorphic grade. Burial of these veined scheelite-bearing rocks to temperatures of ∼500 °C enabled remobilisation of W by metamorphic fluids, concurrent with scavenging of Au, As and S, followed by return of the metal-bearing fluids towards mid to upper crustal levels, where they precipitated scheelite.