Dissolution patterns caused by chemical etching of Al–Co–Cu and Al–Co–Ni decagonal quasicrystals with a HF–HNO3–H2O solution

Abstract

Dissolution patterns essential for Al–Co–Cu and Al–Co–Ni decagonal quasicrystals (d-QCs) have been investigated in detail by chemical etching using a HF–HNO3–H2O solution followed by scanning electron microscopy (SEM) observations. The chemical etching of definite surface areas of the samples, which are either normal or parallel to the tenfold axes, using a solution with HF–HNO3–H2O (1 : 5 : 4 in volume ratio; 0°C; 5–10 min), produces a large number of microfacet pits of decagonal prismatic shape. In addition, the same etching test in combination with SEM observations was carried out on a deformed sample of the Al–Co–Ni d-QC, which had been subjected to concentrated mechanical stress at an elevated temperature of 850°C by means of the Vickers indentation technique. The morphological features of the resulting micropits and their possible origins are discussed on the basis of results obtained by SEM observations.