Abstract

The mechanical properties of the graphite electrode will dynamically change during the charge-discharge cycle, which will affect the propagation characteristics of guided waves in lithium-ion batteries. Meanwhile, lithium-ion batteries experience fluctuations in operating temperature during cycling, which will also influence the propagation of guided waves. This research aims to investigate the guided wave propagation problem of porous electrode material with electrolyte versus temperature. The problem is under the framework of Green-Naghdi theory and Biot theory, and a numerical approach is presented to solve the thermoelastic wave propagation characteristics in such a multi-layered porous electrode. A frequency domain simulation for a multi-layered porous anode will be established. The simulation results confirm the feasibility and accuracy of the proposed approach. The porosity of the anode material shows obvious dynamic variation during cycling, which illustrates a strong correlation with the elastic modulus of the solid skeleton. Then, the effects of porosity and temperature variations on the propagation characteristics of thermoelastic guided waves in multi-layered porous graphite electrodes will be analyzed in detail. The phase velocity of fundamental modes appears regularly shift in the low frequency range. This may provide theoretical support for the acoustic nondestructive characterization of the operating states of the lithium-ion batteries.

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