Dispersion of Birefringence and its Influence on On-Line Measurement of Stresses in Polymer Films

Abstract

Birefringence distribution in biaxially oriented polymer films is often used to assess non-uniformities in processing and in physical properties. Off-line characterization of this property can be performed by direct measurement of anisotropy in the refractive index, a process that is slow and not suitable for on-line use. By comparison, the spectral contents analysis (SCA) method is fast and easily adaptable for on-line process monitoring and real-time process control. However, implementation of this method requires accurate knowledge of the chromatic dispersion of birefringence. This paper discusses the contribution of birefringence dispersion to the precision of birefringence measurements by the SCA method, and it describes a new spectrometric procedure for accurate measurement of this material property.