Dispersion and exfoliation of nanoclays in itaconic acid funcionalized LDPE by ultrasound treatment

Abstract

ABSTRACTPolyethylene–montmorillonite nanocomposites were prepared in the melt applying various ultrasonic powers (231, 347, and 462 W) and temperatures (185, 200, and 215 °C) in the presence of itaconic acid. Dispersion–exfoliation of montmorillonite and in situ low density polyethylene functionalization with itaconic acid were carried out by ultrasound assisted extrusion process. Clay dispersion and exfoliation was evaluated by X‐ray diffraction (XRD) and electronic microscopy (STEM). The degree of grafting itaconic acid into low density polyethylene (LDPE) was determined by infrared analysis (FTIR) and titration technics. Ultrasound‐treated nanocomposites showed improved clay dispersion compared with non‐treated ones. Mechanical properties, XRD, and STEM microscopy indicated that the grafting level, clay dispersion, and exfoliation was directly influenced by IA concentration, temperature, and ultrasonic energy. For instance, the itaconic acid grafted into LDPE was improved from 0.13% to 0.71% when ultrasound power was increased and when temperature was reduced. The modulus was enhanced up to 225 MPa when the ultrasound power was increased up to 462 W. The nanocomposites decomposition temperature, determined by thermogravimetric analysis, was increased nearly 20 °C when 1% w/w itaconic acid was used. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46260.