Abstract

In the title compound, Na2[Ni(C3H2O4)2(H2O)2]·2H2O, the Ni atom is coordinated by four O atoms from two malonate ligands and two water mol­ecules in a distorted octa­hedral geometry. The two independent Na+ ions are coordinated by five and six O atoms, respectively. The crystal structure is stabilized by the three-dimensional hydrogen-bonding network formed by O—H⋯O hydrogen bonds.

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