Abstract
In the title compound, [Ni(C16H18FN3O3)(C14H8O5)(H2O)2]n, the NiII atom exhibits a distorted octahedral geometry that is defined by four O atoms and two water molecules. Ni atoms are connected via the 4,4′-oxydibenzoate anions into a one-dimensional chain running along the crystallographic [30] direction. In the crystal structure, the one-dimensional chains are connected via N—H⋯O and O—H⋯O hydrogen bonding to form a three-dimensional supramolecular network.
Highlights
In the title compound, [Ni(C16H18FN3O3)(C14H8O5)(H2O)2]n, the NiII atom exhibits a distorted octahedral geometry that is defined by four O atoms and two water molecules
Ni atoms are connected via the 4,40-oxydibenzoate anions into a onedimensional chain running along the crystallographic [230] direction
The one-dimensional chains are connected via N—HÁ Á ÁO and O—HÁ Á ÁO hydrogen bonding to form a three-dimensional supramolecular network
Summary
Key indicators: single-crystal X-ray study; T = 298 K; mean (C–C) = 0.004 A; R factor = 0.040; wR factor = 0.112; data-to-parameter ratio = 12.6. In the title compound, [Ni(C16H18FN3O3)(C14H8O5)(H2O)2]n, the NiII atom exhibits a distorted octahedral geometry that is defined by four O atoms and two water molecules. Ni atoms are connected via the 4,40-oxydibenzoate anions into a onedimensional chain running along the crystallographic [230] direction. The one-dimensional chains are connected via N—HÁ Á ÁO and O—HÁ Á ÁO hydrogen bonding to form a three-dimensional supramolecular network. Related literature For general background, see: Xiao et al (2005).
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