Abstract
Several (3 + 2) cycloaddition reactions catalyzed by dirhodium(II) complexes between N-arylaminocyclopropane and alkenes derivative have been developed. Preliminary mechanism studies suggest that dirhodium(II) complexes may decrease the bond-dissociation energy (BDE) of the N-H bond of N-arylaminocyclopropanes for N-H bond activation, thus facilitating the formation of N-centered radicals by loss of a hydrogen radical.
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