Abstract
The construction of two types of coordination polymers with closely related 4-connected topologies [PtS and lvt (4(2).8(4))] were achieved based on a well-designed bent dipyrazine linker, and the topological differences only result from the stereochemistry of silver(I) coordination sphere with the same coordination donors. Selective anion-exchange functions of the series of PtS-type coordination networks containing different counter anions (from small BF4- to very large SbF6-) were identified.
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