Abstract
The electronic effects of substitutents on the values of monomer reactivity ratios in copolymerization of styrene with substituted styrenes have been isolated. The most important proved to be the direct polar conjugation of the substitutent with the nucleophilic reaction centre. A two-parameter correlation equation has been proposed which describes satisfactorily the experimentally determined reactivity of comonomers. The values of monomer reactivity ratios have been determined for copolymerization of styrene with para and meta-substituted aminostyrenes.
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