Abstract

Most high-power electric fuses installed in DC distributions of automobiles employ silica sand (chemical formula SiO2) as arc quenching material to implement the limitation and subsequent interruption of high direct currents. This paper on arc quenching material describes the effects of the addition of silicone resin (chemical formula C2H6SiO) on SiO2 sand, based on the resistance of an arc discharge in SiO2 vapor mixed with silicone resin vapor. The measurement results obtained for the fuse operation of a model electric fuse show that the addition of silicone resin, e.g. an even coating of silicone resin on the surface of a Cu fuse element, attains a shorter arc quenching time. This phenomenon is subsequently explained based on the rise effect of an arc column resistance achieved by mixing with silicone vapor decomposition. The chemical compositions of high-temperature SiO2 vapor mixed with C2H6SiO vapor decomposition are evaluated to show the predominant chemical species at 30 000 K–5000 K for several C2H6SiO vapor concentrations, . The results obtained for of 10%–50% reveal that a H atom originating from C2H6SiO is present at high molar fractions above 0.1 over a wide temperature range of 12 000 K–5000 K. Further evaluations of the electrical resistivity for the high-temperature vapor show that mixing with C2H6SiO vapor contributes to a rise in at temperatures of 10 000 K–6000 K. A contribution analysis of the reveals that the rise effect of the is accomplished chiefly by the presence of a H atom that has dissociated from C2H6SiO.

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