Abstract
AbstractHighly dispersed Pd nanoparticles encapsulated in the mesoporous metal–organic framework MIL‐101 demonstrated high activity and selectivity for the direct C2 arylation of various indoles with aryl boronic acids using O2 or 2,2,6,6‐tetramethylpiperidine N‐oxyradical as an external oxidant in acidic media under mild conditions. The green catalyst is easily recoverable and can be reused six times without leaching and loss of activity.
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