Abstract
The fundamental band of CF+ in the X 1Σ+ state has been observed by infrared diode laser spectroscopy with magnetic field modulation of the dc discharge plasma. The CF+ ion was generated by a hollow cathode discharge in a mixture of CF4 and H2. From an analysis of the observed spectra, the following molecular constants were obtained: ν0=1766.3589(9), Be =1.720 366(81), αe =0.018 947(96), De =6.179(17)×10−6 in cm−1 unit and re =1.154 272(35) Å, with three standard errors in parentheses.
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