Abstract
The linear HBF + ion has been detected for the first time in a dc discharge plasma of a BF 3/H 2 mixture by infrared diode laser spectroscopy with magnetic field modulation. The ν 3 band origin and rotational constants of H 11BF + were determined to be ν 0 = 1633.2241(12), B = 1.211623(42) and B' = 1.203006(43), in cm −1 units with three standard deviations in parentheses.
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