Abstract
A series of cadmium(II) thiolate complexes with urea units [(bpy)2Cd(μ-SC6H4-4-NHC(O)NHC6H4-R-4)]2(ClO4)2 (R=NO2 (1), Cl (2), H (3); bpy=2,2′-bipyridine), have been synthesized and characterized. The crystal structure of 3·(DMF)2 has been determined by X-ray diffraction. The photophysical properties and anion binding properties of 1–3 have been studied.
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