Abstract
Four new thiophosphoryl ligands containing NNPS or CNPS connectivities have been prepared and three of them characterised by single-crystal X-ray diffraction. The complexation of these ligands with salts of CuI, CuII, NiII and ZnII has been studied by electrospray mass spectrometry and uv-visible spectrophotometry in acetonitrile and methanol solution. Evidence for 1∶1 and 2∶1 complexation is presented. Two copper(I) complexes were isolated including a mixed chloride–bromide copper(I) complex in which a dimeric structure is adopted with a 22-membered metallacycle.
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