Abstract

The standard free energy of formation of Bi 2O 3 was measured by means of the solid oxide galvanic cell, yielding ▪ The diffusivity and activity coefficient of oxygen in liquid bismuth for an unsaturated BiO liquid solution were determined from coulemetric titration experiments, which were performed in the temperature range 951–1100 K. The diffusivity is ▪ while the standard free energy of dissolution of oxygen in liquid bismuth, calculated for the reaction ▪ is ▪ Finally, the saturation solubility was calculated and the respective equations took the forms ▪

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