Abstract
The experimentally observed reduction of chemiluminescence in the spiro-substituted dioxetane with increasing diffusion is analyzed in terms of the diffusional theory of spin-dependent recombination and separation of radical ions produced by chemically initiated decomposition of the source reactant. The partitioning between singlet and triplet products of recombination crucially depends on the spin conversion in the radical ion pair and the relative rates of the competing reactions of backward transfer to the excited singlet (light emitting) or triplet state of the recombination products.
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