Abstract

Abstract An accelerated field measurements program was conducted to quantify atmospheric diffusion within a deep, steep-walled canyon in rough, mountainous terrain. Two principle objectives were pursued: impaction of plumes upon elevated terrain, and diffusion of gases within the canyon versus diffusion over flat, open terrain. Oil fog flow visualizations provided qualitative information; quantitative diffusion measurements were obtained using sulfur hexafluoride gas with analysis by highly sensitive gas phase coulometric techniques. Eleven 45 to 60 min gaseous tracer releases were conducted. Stability-category-related differences in canyon diffusion versus flat terrain diffusion were found. Daytime lapse conditions showed little difference. Neutral stability tests showed five times greater dilution for canyon axial concentrations; strong inversion tests resulted in canyon plume centerline dilutions fifteen times greater than calculations using parameters derived for flat terrain. Plume effluents frequent...

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