Abstract
The diffusion coefficients of iodide in water solutions containing NaHSO 4 as supporting electrolyte have been measured between 102 and 215 °C using a high-temperature wall-tube cell. The temperature behavior of the diffusion coefficients is well described by the Arrhenius law and the activation energy for the mass transport is 17 kJ mol −1. The results are compared to those calculated from the iodide conductivity at infinite dilution and to recent results from other authors. The solvation and speciation of the iodide ion in aqueous solutions at high temperature are analyzed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
