Abstract
The solvation of infinitely dilute CsBr in high-temperature aqueous solutions is analysed by integral equation calculations, according to the recently proposed molecular-based formalism which connects the solvent environment around individual ionic species and their macroscopic solvation behaviour. Recent experimental data for infinitely dilute CsBr aqueous solutions are interpreted via the same formalism and compared with their analogous integral equation calculations. Finally, some relevant theoretical implications regarding the modelling of high-temperature aqueous electrolyte solutions are discussed and illustrated by integral equation results.
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