Abstract
1. By the reaction of allylamine and of diallylamine with diethyl (dichloromethylene)phosphoramidate, diethyl (bisallylaminomethylene)- and (bisdiallylaminomethylene)-phosphoramidates were obtained respectively. 2. The chlorine atoms of diethyl (dichloromethylene)phosphoramidate were replaced successively by allylamino and dimethylamino, by diallylamino and dimethylamino or diethylamino, and by diallylamino and ethoxyl, and the products — substituted (diaminomethylene)- and (aminoethoxymethylene)-phosphoramidic esters — were characterized. 3. When dimethylamine reacts with ethyl (dichloromethylene)phosphoramidochloridate, all the chlorine atoms are replaced by dimethylamino groups. 4. Replacement of the chlorine atoms of diethyl (dichloromethylene)phosphoramidate by (ethoxycarbonylmethyl)amino groups with subsequent distillation of the reaction product leads to a cyclic phosphorylated guanidine.
Published Version
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