Abstract
AbstractDiels–Alder reactions and hetero Diels–Alder reactions play crucial role in building complexity in many naturally occurring isoprenoids. A number of structurally intriguing complex isoprenoids have been isolated form Nature, those are believed to follow a [4+2]‐cycloaddition reaction in their biosynthetic proposal. In this focus review, we discuss on the recent efforts on biomimetic total syntheses of complex isoprenoids utilizing Diels–Alder and hetero Diels–Alder reactions. In particular, we have considered isoprenoids arising from a basic icetaxane, abietane, dinor‐abietane, and abeo‐abietane structural scaffolds.
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