Abstract

Flexible electronics have gained eminent importance in recent years due to their high mechanical strength and resistance to environmental conditions, along with their effective energy storage and energy generating abilities. In this work, graphene/ceramic/polymer based flexible dielectric nanocomposites have been prepared and their dielectric properties were characterized. The composite was formulated by combining graphene with rutile and anatase titania, and polyvinylidene fluoride in different weight ratios to achieve optimized dielectric properties and flexibility. After preparation, composites were characterized for their morphologies, structures, functional groups, thermal stability and dielectric characterizations by using scanning electron microscopy, X-ray diffraction, Raman spectroscopy, Fourier transform infrared spectroscopy, thermal gravimetric analysis and impedance spectroscopy. Dielectric results showed that prepared flexible composite exhibited dielectric constant of 70.4 with minor leakage current (tanδ) i.e., 0.39 at 100 Hz. These results were further confirmed by calculating alternating current (AC) conductivity and electric modulus which ensured that prepared material is efficient dielectric material which may be employed in electronic industry for development of next generation flexible energy storage devices.

Highlights

  • Flexible electronics are attracting increased attention in the electronic industry day by day due to their compact nature and ease of handling

  • It is evident that graphene sheets are segregated rather evenly distributed in the polymer

  • It is evident that graphene sheets are segregated rather than being than being aligned due to occurrence of TiO2 and PVDF

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Summary

Introduction

Flexible electronics are attracting increased attention in the electronic industry day by day due to their compact nature and ease of handling. Polymers are attractive to synthesize flexible materials but they have limitations of low capacitance and low dielectric constants [4]. In last few years efforts have been made to enhance dielectric constant (ε0 ) of polymers either by using dielectric or conducting fillers [5,6]. Conducting fillers can elevate ε0 to a much higher value, but the amount of conducting filler plays a critical role in this increase. The dielectric response of conducting filler/polymer composites depends upon the percolation phenomenon. In such composites if the concentration of conducting filler is Materials 2020, 13, 205; doi:10.3390/ma13010205 www.mdpi.com/journal/materials

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