Abstract

Abstract The permittivity and dielectric loss of acetyl acetone, benzoyl acetone and dibenzoyl methane have been measured at four microwave frequencies viz., 30.20, 24.50, 18.26, and 9.83 GHz and also at 1 MHz and optical frequency at 35 °C. The permittivity and dielectric loss at different frequen­ cies have been plotted against concentration (wt. fraction). The slopes of these straight lines have been used for the complex plane plots (a″ vs. a′). The complex plane plots for these compounds are Cole-Cole arcs. The dielectric relaxation time (τ0) and distribution parameter (α) have been calculated from these plots. Data have been analysed in terms of two relaxation processes i. e., cor­ responding to overall rotation and group rotation. The dipole moments of these molecules are reported.

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