Abstract

A series of Zr4+ doped MgFe2O4 samples (Mg1-xFe2O4: xZr (x = 0, 0.25, 0.5, 0.75, 1, 1.25 and 1.5 mol %) were synthesized using the solid-state reaction method. The XRD analysis confirms that the prepared sample has single phase cubic spinel structure with Fd-3m space group. The average crystallite size of the sample has been found to be 28.2 nm. The SEM image shows irregular cubical grains with agglomerated morphology, while the EDX spectrum confirms the presence of all essential elements. The dielectric constant and dielectric loss decrease at higher frequencies due to decreased polarization. The Complex impedance spectroscopy confirmed the existence of electrical relaxation phenomenon, and the Cole-Cole plot indicates the grain boundary contribution. The AC conductivity value remains constant at a low frequency range but shifts towards the higher value in the higher frequency region. The calculated activation energy values range from 0.27 to 0.55 eV.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.