Abstract

We report on findings in the HoFe3(BO3)4 single crystal across structural phase transition by the dielectric and Raman spectroscopic measurements. In most of the compounds of RFe3(BO3)4 (R=La-Lu) family low temperature P3121 structure is introduced through structural phase transition (from space group R32). Temperature dependent dielectric measurements on the HoFe3(BO3)4 crystal depicts a step like feature at the structural phase transition at ∼366 K. The Raman spectroscopy study also confirms the structural transition around this temperature. A clear signature of structural transition is reflected in the Raman spectra, mainly in the frequency range (200-400 cm-1). Appearance of new Raman modes below the transition temperature also indicates that the transition is from a high symmetry phase to a low symmetry phase.

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