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Abstract
Molecules of the title compound, [Sn(C7H6Cl)2Cl2], lie on a twofold rotation axis which passes through the Sn atom. The SnIV atom exists in a distorted tetrahedral geometry. Adjacent molecules are linked by weak Sn⋯Cl contacts [3.703 (1) Å], forming a linear chain motif extending along the b axis.
Highlights
Z=4 Mo K radiation = 2.34 mmÀ1 T = 100 K 0.40 Â 0.10 Â 0.10 mm 8736 measured reflections 1767 independent reflections 1674 reflections with I > 2(I) Rint = 0.029
Molecules of the title compound, [Sn(C7H6Cl)2Cl2], lie on a twofold rotation axis which passes through the Sn atom
The SnIV atom exists in a distorted tetrahedral geometry
Summary
Received 13 July 2010; accepted 14 July 2010 Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.005 A; R factor = 0.027; wR factor = 0.073; data-to-parameter ratio = 20.3. Monoclinic, C2=c a = 26.0750 (13) Ab = 4.7757 (2) Ac = 13.3389 (7) A = 112.1538 (5) V = 1538.42 (13) A 3
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