Abstract
The title compound, [{CpFe(CO)2}2Sn{S2CN(C4H9-i)2}2] or [SnFe2(C5H5)2(C9H18NS2)2(CO)4], is obtained from the reaction of [C5H5Fe(CO)2]2SnCl2 and potassium N,N-diisobutyldithiocarbamate in a mixed solvent (C6H6–THF 1:1). The crystal structure shows that the Sn atom is situated on a twofold rotation axis. An Fe—Sn—Fe cluster is present in the complex, the Sn and Fe atoms having coordination numbers 4 and 8, respectively. There are non-conventional intramolecular C—H⋯S and C—H⋯N hydrogen bonds in the structure.
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More From: Acta Crystallographica Section E Structure Reports Online
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