Abstract

In the title compound, [CdCl2(C12H12N2)], the CdII atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and two terminal Cl atoms. Inter­molecular C—H⋯Cl hydrogen bonds and π–π stacking inter­actions between the pyridyl rings [centroid–centroid distance = 3.7337 (18) Å] are present in the crystal structure.

Highlights

  • In the title compound, [CdCl2(C12H12N2)], the CdII atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 6,60 -dimethyl-2,20 -bipyridine ligand and two terminal Cl atoms

  • We report the synthesis and crystal structure of the title compound

  • Crystals suitable for X-ray diffraction experiment were obtained by methanol diffusion into a colorless solution of the title compound in DMSO after one week

Read more

Summary

Bruker SMART APEX CCD diffractometer

Vahid Amanib a School of Chemistry, Damghan University, Damghan, Iran, and bIslamic Azad. R factor = 0.033; wR factor = 0.086; data-to-parameter ratio = 23.7. In the title compound, [CdCl2(C12H12N2)], the CdII atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a 6,60 -dimethyl-2,20 -bipyridine ligand and two terminal Cl atoms. Intermolecular C—H Cl hydrogen bonds and – stacking interactions between the pyridyl rings [centroid–centroid distance = 3.7337 (18) Å] are present in the crystal structure

Related literature
Mo K radiation
Graphite monochromator φ and ω scans
Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call