Abstract
In the title compound, [VClO(C12H12N2)2]Cl·C2H5OH·H2O, the VIV atom is six-coordinated in a distorted octahedral geometry by four N atoms from two 4,4′-dimethyl-2,2′-bipyridine ligands, one O atom and one Cl atom. In the crystal, O—H⋯Cl, C—H⋯O and C—H⋯Cl hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distances = 3.7236 (17) and 3.6026 (19) Å] stabilize the structure. Intramolecular C—H⋯O and C—H⋯Cl hydrogen bonds are also present.
Highlights
In the title compound, [VClO(C12H12N2)2]ClC2H5OHH2O, the VIV atom is six-coordinated in a distorted octahedral geometry by four N atoms from two 4,40 -dimethyl-2,20 bipyridine ligands, one O atom and one Cl atom
We report the synthesis and crystal structure of the title compound, (I)
In the title compound (Fig. 1), the VIV atom is six-coordinated in a distorted octahedral geometry by four N atoms from two 4,4′-dmbipy ligands, one O atom and one Cl atom
Summary
Data collection cis-Chloridobis(4,40 -dimethyl-2,20 -bipyridine-j2N,N0 )oxidovanadium(IV) chloride ethanol monosolvate monohydrate. Shirvan,a* Sara Haydari Dezfuli,a Elyas Golabib and Mohammad Amin Gholamzadehb a Department of Chemistry, Islamic Azad University, Omidieh Branch, Omidieh, Iran, and bDepartment of Petroleum Engineering, Islamic Azad University, Omidieh. R factor = 0.062; wR factor = 0.144; data-to-parameter ratio = 16.3. In the title compound, [VClO(C12H12N2)2]ClC2H5OHH2O, the VIV atom is six-coordinated in a distorted octahedral geometry by four N atoms from two 4,40 -dimethyl-2,20 bipyridine ligands, one O atom and one Cl atom. O—H Cl, C—H O and C—H Cl hydrogen bonds and – contacts between the pyridine rings [centroid–centroid distances = 3.7236 (17) and 3.6026 (19) Å].
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