Abstract
Metal 1,3-diketonates are known to undergo many electrophilic substitutions typical of aromatic compounds because of the quasi-aromatic C 3 O 2 M ring systems present in these chelates. Although the aryldiazonium ion is a dominant electrophile (its coupling with free 1,3-diketones is an electrophilc substitution), reports are scanty on its reaction with metal-chelated 1,3-diketones. In this paper, we report the electrophilic substitution of the phenyldiazonium ion at 2,4-pentanedionates of aluminium(III), chromium(III), copper(II) and palladium(II)
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