Abstract
The title complex, [Ni(N3)2(C10H8N2)(CH3OH)2], lies on a twofold roation axis which runs through the NiII ion and the mid-point of the bipyridine ligand. The NiII ion is coordinated in a distorted octahedral environment by two azide ligands in a trans configuration. The methanol ligands are in a cis configuration and their hydroxy groups form intramolecular O—H⋯(N,N) hydrogen bonds with the azide ligands.
Highlights
The title complex, [Ni(N3)2(C10H8N2)(CH3OH)2], lies on a twofold roation axis which runs through the NiII ion and the mid-point of the bipyridine ligand
The NiII ion is coordinated in a distorted octahedral environment by two azide ligands in a trans configuration
The methanol ligands are in a cis configuration and their hydroxy groups form intramolecular
Summary
R factor = 0.058; wR factor = 0.210; data-to-parameter ratio = 12.6. The title complex, [Ni(N3)2(C10H8N2)(CH3OH)2], lies on a twofold roation axis which runs through the NiII ion and the mid-point of the bipyridine ligand. The NiII ion is coordinated in a distorted octahedral environment by two azide ligands in a trans configuration. The methanol ligands are in a cis configuration and their hydroxy groups form intramolecular. O—H (N,N) hydrogen bonds with the azide ligands
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