Azido(benzoylacetonato-κ2O,O′)[1-phenyl-3-(2-pyridylmethylimino)but-1-en-1-olato-κ3N,N′,O]cobalt(III)

Amitabha Datta,Jui-Hsien Huang,Ming-Han Sie,Hon Man Lee

doi:10.1107/s1600536810003338

Amitabha Datta, Jui-Hsien Huang + Show 2 more

Open Access

https://doi.org/10.1107/s1600536810003338

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Abstract

In the title complex, [Co(C16H15N2O)(C10H9O2)(N3)], the CoII atom adopts an octahedral coordination geometry by a tridentate Schiff base, a bidentate benzoylacetonate and an azide ligand. The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate ligand and the azide ligand is trans to the acetyl O atom of the bidentate ligand. Non-classical intramolecular Caryl—H⋯O hydrogen bonds are present in the structure.

Highlights

In the title complex, [Co(C16H15N2O)(C10H9O2)(N3)], the CoII atom adopts an octahedral coordination geometry by a tridentate Schiff base, a bidentate benzoylacetonate and an azide ligand
The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate ligand and the azide ligand is trans to the acetyl O atom of the bidentate ligand
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)