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https://doi.org/10.1016/j.tetasy.2012.10.019
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Cite Journal: Tetrahedron: Asymmetry |  Publication Date: Dec 1, 2012 |
 Citations: 12 |
Affiliation: Ohu University, Tokyo University of Pharmacy and Life Sciences
The diastereoselective synthesis of Pro-Phe phosphinyl dipeptide isosteres in protected form was achieved by starting from optically active 1,1-diethoxyethyl(aminomethyl)phosphinate. Our methodology involves diastereoselective α-alkylation and β′-alkylation of phosphinate derivatives with an asymmetric center at the phosphorus atom.
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