Abstract

In the title complex, [Cu(C9H6N2O5)(H2O)2]·2H2O, the CuII atom has a square-pyramidal coordination environment with a tridentate N-(5-nitro-2-oxidobenzyl­idene)glycinate Schiff base ligand and a water mol­ecule in the basal plane. The apical site is occupied by an O atom from another coordinated water mol­ecule. The crystal structure is stabilized by O—H⋯O hydrogen bonds, building a two-dimensional network parallel to (100).

Highlights

  • In the title complex, [Cu(C9H6N2O5)(H2O)2]2H2O, the CuII atom has a square-pyramidal coordination environment with a tridentate N-(5-nitro-2-oxidobenzylidene)glycinate Schiff base ligand and a water molecule in the basal plane

  • H atoms treated by a mixture of independent and constrained refinement max = 0.53 e Å3

  • The apical site is occupied by an O atom from another coordinated water molecule

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Summary

Republic of China

H O hydrogen bonds, building a two-dimensional network parallel to (100)

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