Abstract
In the title complex, {[Na(C7H7N2O4)(H2O)2]·H2O}n, the NaI atom exhibits a distorted octahedral geometry and is six-coordinated in an NO5 environment. The equatorial plane is defined by three O atoms and one N atom from two distinct 5-carboxy-2-ethyl-1H-imidazole-4-carboxylate (H2EIDC) ligands and one coordinated water molecule, and the apical sites are occupied by one carboxyl O atom from one H2EIDC ligand and one O atom from the other coordinated water molecule. The NaI atoms are linked by H2EIDC ligands, generating an infinite double chain along the a axis. These chains are further connected via O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional supramolecular network.
Highlights
In the title complex, {[Na(C7H7N2O4)(H2O)2]H2O}n, the NaI atom exhibits a distorted octahedral geometry and is sixcoordinated in an NO5 environment
The equatorial plane is defined by three O atoms and one N atom from two distinct
The NaI atoms are linked by H2EIDC ligands, generating an infinite double chain along the a axis
Summary
Experimental a College of Food Science and Technology, Guangdong Ocean University, Zhanjiang. University, Zhanjiang 524088, People’s Republic of China, and cCollege of Agriculture, Guangdong Ocean University, Zhanjiang 524088, People’s Republic of. The equatorial plane is defined by three O atoms and one N atom from two distinct. Ligands and one coordinated water molecule, and the apical sites are occupied by one carboxyl O atom from one H2EIDC ligand and one O atom from the other coordinated water molecule. The NaI atoms are linked by H2EIDC ligands, generating an infinite double chain along the a axis. These chains are further connected via O—H O and N—H O hydrogen bonds into a three-dimensional supramolecular network
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