Abstract
The dinuclear title complex, [Ag2Cl2(CH5N3S)2(C18H15P)2], lies across an inversion center. The AgI ion exhibits a slightly distorted tetrahedral coordination geometry formed by a P atom from a triphenylphosphane ligand, two metal-bridging S atoms from thiosemicabazide ligands and one chloride ion. The S atoms bridge two symmetry-related AgI ions, forming a strictly planar Ag2S2 core with an Ag⋯Ag separation of 2.7802 (7) Å. There is an intramolecular N—H⋯Cl hydrogen bond. In the crystal, N—H⋯Cl and N—H⋯S hydrogen bonds link complex molecules, forming layers parallel to (001). These layers are connected through π–π stacking interactions [centroid–centroid distance = 3.665 (2) Å], leading to the formation of a three-dimensional network.
Highlights
The dinuclear title complex, [Ag2Cl2(CH5N3S)2(C18H15P)2], lies across an inversion center
H atoms treated by a mixture of independent and constrained refinement max = 0.38 e Å3
Symmetry codes: (ii) x−1, y, z; (iii) −x+1, −y+2, −z+1; (iv) −x+2, −y+3, −z+1
Summary
R factor = 0.026; wR factor = 0.069; data-to-parameter ratio = 20.0. The dinuclear title complex, [Ag2Cl2(CH5N3S)2(C18H15P)2], lies across an inversion center. The AgI ion exhibits a slightly distorted tetrahedral coordination geometry formed by a P atom from a triphenylphosphane ligand, two metal-bridging S atoms from thiosemicabazide ligands and one chloride ion. The S atoms bridge two symmetry-related AgI ions, forming a strictly planar Ag2S2 core with an Ag Ag separation of. There is an intramolecular N—H Cl hydrogen bond. N—H Cl and N—H S hydrogen bonds link complex molecules, forming layers parallel to (001). These layers are connected through – stacking interactions [centroid–centroid distance = 3.665 (2) Å], leading to the formation of a three-dimensional network
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