Abstract
The molecule of the title compound, [Ti2(CH3)2(CH3O)2(C11H15O)4] or {[Ti(Me)(μ-OCH3)(OC6H3CMe3-2-Me-6)]2}, has a centrosymmetric, dimeric structure with a distorted square pyramidal array about each titanium atom. The methoxide ligands form an asymmetric bridge between the two TiIV atoms [Ti—O bond lengths of 1.9794 (12) and 2.0603 (12) Å] with the two phenolato ligands occupying the remaining basal sites [Ti—O 1.8218 (11) and 1.8135 (11) Å]. The Ti—O—C phenolato bond angles are similar at 161.24 (10) and 160.66 (11)°. The methyl ligand attached to the metal atom has a Ti—C bond length of 2.0878 (17) Å.
Highlights
Experimental a Crystal dataChemistry, Institute of Fundamental Sciences, Massey University at Albany, PO Box 102904 North Shore Mail Centre, Auckland, New Zealand
Chemistry, Institute of Natural and Mathematical Sciences, Massey University at Albany, PO Box 102904 North Shore Mail Centre, Auckland, New Zealand, and b
The methyl ligand attached to the metal atom has a Ti—C bond length of 2.0878 (17) Å
Summary
Chemistry, Institute of Fundamental Sciences, Massey University at Albany, PO Box 102904 North Shore Mail Centre, Auckland, New Zealand. R factor = 0.034; wR factor = 0.089; data-to-parameter ratio = 18.4. The molecule of the title compound, [Ti2(CH3)2(CH3O)2(C11H15O)4] or {[Ti(Me)(-OCH3)(OC6H3CMe3-2-Me-6)]2}, has a centrosymmetric, dimeric structure with a distorted square pyramidal array about each titanium atom. The methoxide ligands form an asymmetric bridge between the two TiIV atoms [Ti—O bond lengths of 1.9794 (12) and. 2.0603 (12) Å] with the two phenolato ligands occupying the remaining basal sites [Ti—O 1.8218 (11) and 1.8135 (11) Å]. The methyl ligand attached to the metal atom has a Ti—C bond length of 2.0878 (17) Å
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