Abstract
The dimeric title compound, [Cu2(C9H10N3O)2(N3)2], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical intermolecular C—H⋯N hydrogen bonds link the dimers into chains along the c axis.
Highlights
The dimeric title compound, [Cu2(C9H10N3O)2(N3)2], is located on a crystallographic inversion center
The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry
Non-classical intermolecular C—H N hydrogen bonds link the dimers into chains along the c axis
Summary
National Changhua University of Education, Department of Chemistry, Changhua, Taiwan 50058. R factor = 0.027; wR factor = 0.093; data-to-parameter ratio = 15.1. The dimeric title compound, [Cu2(C9H10N3O)2(N3)2], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. Non-classical intermolecular C—H N hydrogen bonds link the dimers into chains along the c axis
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