Abstract

AbstractEvanescent wave‐based excitation of noble metal nanostructures on fiber core surface allows simultaneous excitation over a larger area in comparison with free space coupling, and hence highly suitable for development of surface‐enhanced Raman scattering (SERS)‐based sensor applications. This study describes the development of plasmonically active U‐bent plastic optical fiber (POF) probes for SERS‐based sensing. The SERS activity of gold nanostructures on the fiber probe surface obtained by means of electroless deposition, sputtering, and chemisorption of nanoparticles are thoroughly characterized using a confocal microscopic setup. Influence of excitation wavelength and laser excitation power on SERS activity and stability of the plasmonic U‐bent probes is evaluated. Gold‐sputtered POF probes and gold nanoparticle immobilized POF probes show higher enhancement factor in the order to ~108. A biosensor application of these POF‐based SERS sensors is demonstrated by realizing a sandwich immunoassay with 4‐MBA as Raman label.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call