Development of Nanocomposite Film Comprising of Polyvinyl Alcohol (PVA) Incorporated with Bacterial Cellulose Nanocrystals and Magnetite Nanoparticles.

Somwang Khantayanuwong,Naphat Usawattanakul,Selorm Torgbo,Buapan Puangsin,Prakit Sukyai,Preeyanuch Srichola

doi:10.3390/polym13111778

Somwang Khantayanuwong, Naphat Usawattanakul + Show 4 more

Open Access

https://doi.org/10.3390/polym13111778

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Journal: Polymers	Publication Date: May 28, 2021
Citations: 24	License type: CC BY 4.0

Affiliation: Kasetsart University

Abstract

Nanocomposite film of poly(vinyl alcohol) (PVA) incorporated with bacterial cellulose nanocrystals (BCNCs) and magnetite nanoparticles (Fe3O4) is reported in this study. The BCNC-Fe3O4 nanoparticles and PVA film was prepared by in situ synthesis technique using chemical co-precipitation. Different concentrations of BCNC-Fe3O4 (20%, 40% and 60% w/w) were mechanically dispersed in PVA solution to form the nanocomposite film. Transmission electron microscopy (TEM) analysis of BCNC-Fe3O4 nanoparticles showed irregular particle sizes ranging from 4.93 to 30.44 nm with an average size distribution of 22.94 nm. The presence of characteristic functional groups of PVA, BCNC and Fe3O4 were confirmed by Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD) analysis. Scanning electron microscope (SEM) attached energy dispersive spectroscopy (EDS) and vibrating sample magnetometer (VSM) analysis revealed that, the iron content and magnetic property increased with increasing BCNC-Fe3O4 content. The saturation magnetizations (MS) value increased from 5.14 to 11.56 emu/g. The PVA/ BCNC-Fe3O4 at 60% showed the highest Young’s modulus value of 2.35 ± 0.16 GPa. The prepared film could be a promising polymeric nanomaterial for various magnetic-based applications and for the design of smart electronic devices.

Highlights

Magnetite nanoparticles (Fe3 O4 ) are stimuli responsive materials that have gained much attention from researchers worldwide
Prior to the synthesis of BM, the shape and size of bacterial cellulose nanocrystals (BCNCs) and Fe3 O4 nanoparticles were analyzed by atomic force microscopy, which presented varied morphologies of BCNC and Fe3 O4 (Supplementary Materials Figure S1)
The X-ray diffraction (XRD) and analysis showed the presence of functional groups of poly(vinyl alcohol) (PVA), BCNC and Fe3O4

Summary

Introduction

Magnetite nanoparticles (Fe3 O4 ) are stimuli responsive materials that have gained much attention from researchers worldwide. This is because of its properties such as nanosize, crystallinity, large specific surface area, superparamagnetism and magnetization value [1]. Coating layers may be required to keep the magnetic properties for application in diverse fields [5,6]. In this regard, Yantasee et al prepared superparamagnetic iron oxide (Fe3 O4 ) nanoparticles functionalized with thiol as an effective sorbent material for toxic substances, which have affinity to iron oxide lattices [7]. The use of synthetic compound as a conjugant for magnetic materials in matrices may pose a lot of environmental challenges

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