Abstract
3D printing utilized as a direct deposition of conductive polymeric materials onto textiles reveals to be an attractive technique in the development of functional textiles. However, the conductive fillers—filled thermoplastic polymers commonly used in the development of functional textiles through 3D printing technology and most specifically through Fused Deposition Modeling (FDM) process—are not appropriate for textile applications as they are excessively brittle and fragile at room temperature. Indeed, a large amount of fillers is incorporated into the polymers to attain the percolation threshold increasing their viscosity and stiffness. For this reason, this study focuses on enhancing the flexibility, stress and strain at rupture and electrical conductivity of 3D-printed conductive polymer onto textiles by developing various immiscible polymer blends. A phase is composed of a conductive polymer composite (CPC) made of a carbon nanotubes (CNT) and highly structured carbon black (KB)- filled low-density polyethylene (LDPE) and another one of propylene-based elastomer (PBE) blends. Two requirements are essential to create flexible and highly conductive monofilaments for 3D-printed polymers onto textile materials applications. First, the co-continuity of both the thermoplastic and the elastomer phases and the location of the conductive fillers in the thermoplastic phase or at the interface of the two immiscible polymers are necessary to preserve the flexibility of the elastomer while decreasing the global amount of charges in the blends. In the present work based on theoretical models, when using a two-step melt process, the KB and CNT particles are found to be both preferentially located at the LDPE/PBE interface. Moreover, in the case of the two-step extrusion, SEM characterization showed that the KB particles were located in the LDPE while the CNT were mainly at the LDPE/PBE interface and TEM analysis demonstrated that KB and CNT nanoparticles were in LDPE and at the interface. For one-step extrusion, it was found that both KB and CNT are in the PBE and LDPE phases. These selective locations play a key role in extending the co-continuity of the LDPE and PBE phases over a much larger composition range. Therefore, the melt flow index and the electrical conductivity of monofilament, the deformation under compression, the strain and stress and the electrical conductivity of the 3D-printed conducting polymer composite onto textiles were significantly improved with KB and CNT-filled LDPE/PBE blends compared to KB and CNT-filled LDPE separately. The two-step extrusion processed blends presented the best properties and almost similar to the ones of the textile materials and henceforth, could be a better material for functional textile development through 3D printing onto textiles.
Highlights
Fused Deposition Modeling (FDM), a 3D printing technique, is used to deposit fused conductive thermoplastic polymers onto textile materials, following, for instance, a desired pattern and a defined number of layers
60%(LDPE16.7% KB + 4.2% carbon nanotubes (CNT) )/40 propylene-based elastomer (PBE) blends presented the best properties and almost similar to the ones of the textile materials and could be a better material for functional textile development through 3D printing onto textiles
The main target of this research work is to enhance the flexibility, stress and strain at rupture and electrical conductivity of 3D-printed conductive polymer onto textiles by producing immiscible carbon nanotubes (CNT) and highly structured carbon black known as Ketjenblack (KB)-filled low-density polyethylene (LDPE)/propylene-based elastomer (PBE) blends
Summary
Fused Deposition Modeling (FDM), a 3D printing technique, is used to deposit fused conductive thermoplastic polymers onto textile materials, following, for instance, a desired pattern and a defined number of layers. Eutionnat-Diffo et al [3] studied the stress, strain and deformation under pressure of the 3D-printed polylactic acid (PLA) and carbon-black (CB)-filled PLA onto textiles. They found that the deposition process significantly influences the tensile and deformation properties of the printed polymer onto textile compared to the ones of the textiles [4]. The main target of this research work is to enhance the flexibility, stress and strain at rupture and electrical conductivity of 3D-printed conductive polymer onto textiles by producing immiscible carbon nanotubes (CNT) and highly structured carbon black known as Ketjenblack (KB)-filled low-density polyethylene (LDPE)/propylene-based elastomer (PBE) blends. Deformation under compression, strain and stress and the electrical conductivity of the 3D-printed CPCs/PBE blends onto textiles were explored. The appellation “3D-PPOT conductive materials” means 3D-printed conductive polymers on textiles materials
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