Abstract
The construction of electrodeposited coatings (EDCs) with enhanced microstructural characteristics and superior electrochemical corrosion behavior is of enduring concern for the industrial applications. In this study, alumina (Al2O3) nanoparticles were incorporated into a Ni-Co alloy matrix to improve its morphological and electrochemical behaviors. The primary objective was to assess the impact of varying electrodeposition current densities (20, 40, and 60 mA/m2) and different contents of alumina (3, 5, and 7 g/L) on the properties of a ternary Ni-Co-Al2O3 composite coating. EDX analysis was employed to investigate the effects of deposition current density and alumina bath loading on cobalt/nickel (Co/Ni) ratio and alumina content in the coatings. The results revealed that both the Co/Ni ratio and alumina content in the coatings increased with increasing current density and bath loading, but only up to certain thresholds (40 mA/m2 and 5 g/L). XRD analysis was conducted to assess the phase composition, crystal structure, crystallite size values, and preferred orientation of the fabricated EDCs. The mechanical properties of the deposited coatings were also evaluated using Vickers microhardness testing. The electrochemical corrosion behavior of the as-prepared EDCs was assessed using potentiodynamic polarization (Tafel) and electrochemical impedance spectroscopy (EIS) techniques. The 40 mA/cm2 and 5 g/L samples exhibited lower corrosion current density (jcorr), higher charge transfer resistance (Rct), and lower double layer capacitance (CPEdl) values, suggesting that the increased cobalt and alumina particles in the coatings improved the corrosion resistance. Consequently, the optimal current density and alumina bath content for achieving the most favorable properties were found to be 40 mA/m2 and 5 g/L, respectively.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
