Development of a Modified Bromley's Methodology for the estimation of ionic media effects on solution equilibria: Part 4. The chemical model of Fe(III) with the halide ligands in aqueous solution at 25°C

Abstract

The Modified Bromley's Methodology (MBM) has been used to construct the basic chemical model between Fe(III) and OH − and the halide ligands Cl −, Br − and F − in NaClO 4 medium at 25°C, obtaining the thermodynamic constants and the corresponding interaction parameters for each equilibrium. This basic model has been extended to KNO 3, HCl, and KCl media obtaining the corresponding interaction parameters. The applicability of the model is also discussed.